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Tishchenko hydroacylation

[2 3] sigmatropic rearrangement

[3 2] annulation

[3 4] annulation

[33] sigmatropic rearrangement

[4 2] annulation

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jsuh

jsuh's bookmarks matching tag "benzoin hydroacylation"

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Rh-Catalyzed Carbonyl Hydroacylation: An Enantioselective Approach to Lactones

Zengming Shen, Hasan Khan, and Vy Dong

Journal of the American Chemical Society 130 (10), 2916-7 (16 Feb 2008)

info:doi/10.1021/ja7109025

C-H insertion of aldehyde by rhodium, followed by hydrometalation then reductive elimination gives formal tishchenko-type hydroacylation product.

Posted by jsuh to C-H insertion Tishchenko hydroacylation benzoin hydroacylation lactonization lactone aldehyde rhodium on Wed Mar 19 2008 at 19:28 UTC | info | related

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