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1 2-metalate rearrangement

aldol condensation

aliphatic alcohol

allyl beta-ketoester

allyl carbamothioate

allylic alcohol

allylic alkylation

allylic etherification

allylic nucleophile

alpha-amido aldehyde

alpha-arylation

alpha-halo carbonyl

alpha-haloacrylates

alpha-propargylic conjugated system

arene functionalization

aryl alkynyl ketone

aryl allyl ether

aryl tosyl-mesylate

arylative alkylation

asymmetric deprotonation

azodicarboxylate

azomethine imine

azomethine ylide

baeyer-villiger

benzoin cyclization

benzoin hydroacylation

benzylic halide

bis(pinacolato)dibor- on

brook rearrangement

carbometalation

carboxylic acid

chelation stereocontrol

chiral auxiliary

chiral bronsted acid

cinchona alkaloid

claisen rearrangement

click chemistry

conjugated system

Cope rearrangement

Cross-Metathesis

cyclohexadienone

cycloisomerization

cyclopropanation

decarbonylation

Decarboxylation

dehydrogenation

dialkylidene ketone

dihydropyranone

dihydropyrazole

dihydropyridine

dipolar cycloaddition

directing group

electrocyclic reaction

electrophilic conj. system

enantioselective protonation

friedel-crafts alkylation

Fries rearrangement

gamma-keto acid

heterocycle functionalization

homoallylic amine

homoallylic nitrone

hydroformylation

hydrostannylation

Ireland-Claisen Rearrangement

Lewis base catalysis

macrolactamization

Martin sulfurane

metal carbenoid

meyer-schuster rearrangement

Michael addition

morita-baylis-hillma- n

multi-carbocycle

multi-component reaction

N-acyl dehydroamino ester

N-allylhydrazone

N-tert-butanesulfiny- l

Nazarov cyclization

O-alkyl carbamate

oxidative annulation

oxidative cyclization

Petasis Reaction

phase-transfer catalyst

phosphinooxazoline

Phosphoric acid

phosphorodiamidate

Phosphorylation

pictet-spengler

polar dipolarophilic cyclization

primary alcohol

prins cyclization

propargylic alcohol

proton transfer catalysis

pyridine-N-oxide

pyridinium ylide

radical cyclization

reductive aldol

retro brook rearragement

retro-allylation

reversed reactivity

ring-closing metathesis

silacyclopropane

silylene transfer reaction

Sommelet-Hauser rearrangement

sulfonylimidate

tandem transformation

tetrahydropyran

Tishchenko hydroacylation

trifluoroborate

[2 3] sigmatropic rearrangement

[3 2] annulation

[3 4] annulation

[33] sigmatropic rearrangement

[4 2] annulation

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Catalytic Asymmetric Synthesis of Allylic Aryl Ethers

Stefan Kirsch et al.

Organic Letters 9 (5), 911-3 (03 Feb 2007)

info:doi/10.1021/ol070110b

Pd(II) catalyzed enantioselective allylic etherification of allylic trichloroacetimidate with phenol to generate 3-aryloxy, 1-alkene is described. Regioselectivity is excellent with preference for branched product.

Posted by jsuh to palladium aryl allyl ether acetimidate allylic etherification Cobalt on Mon May 05 2008 at 23:07 UTC | info | related

Au-Catalyzed Cyclization of Monoallylic Diols

Aaron Aponick, * Chuan-Ying Li, and Berenger Biannic

Organic Letters 10 (4), 669-71 (2008)

info:doi/10.1021/ol703002p

Gold/Silver catalyzed cyclization of allylic diol to generate 2-vinyltetrahydropyran.

Posted by jsuh to allylic diol silver tetrahydropyran gold alkene allylic etherification on Mon Feb 25 2008 at 19:27 UTC | info | related

Palladium-(S,pR)-FerroNPS-Catalyzed Asymmetric Allylic Etherification: Electronic Effect of Nonconjugated Substituents on Benzylic Alcohols on Enantioselectivity

Fuk Loi Lam et al.

Angewandte Chemie International Edition 47 (7), 1280-3 (2008)

info:doi/10.1002/anie.200703955

Posted by jsuh to allylic etherification on Sat Feb 09 2008 at 01:55 UTC | info | related

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