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From DNA cross-linking to peptide labeling: on the versatility of the furan-oxidation–conjugation strategy
Chemical Communications (3), 340 (2009)
 
Base-Catalyzed Diels−Alder Reactions of 2H-Pyran-2,5-diones: A Mild Approach to Basiliolide B
Xiongfei Zhou et al.
Organic Letters
Note the usage of furfural as a synthetic tool to access pyrandione via a sequence of bromination and Jones oxidation of the resultant hemi-acetal.
Posted by jsuh to pyrandiones furan diels-alder on Tue Nov 18 2008 at 20:58 UTC | info | related
 
Au-Containing All-Carbon 1,3-Dipoles: Generation and [3+2] Cycloaddition Reactions
Journal of the American Chemical Society 130 (38), 12598 (2008)
Gold catalyzed rearrangement of propargylic ketal/acetal to 1,3-dipoles that react with enones/enals and N-benzylindole to give the formal [3+2] cycloadducts, dihydrofurans and cyclopentenes.
 
Highly Enantioselective Synthesis of 2-Furanyl-hydroxyacetates from Furans via the Friedel−Crafts Reaction
Organic Letters 10 (14), 2955 (2008)
Ti(OiPr)4/binol catalyzed friedel-crafts alkylation of furans with glyoxalates to afford alpha-furfuryl, alpha hydroxyl esters in good ee.
 
Organocatalytic Vinyl and Friedel-Crafts Alkylations with Trifluoroborate Salts
Sandra Lee and David MacMillan
Journal of the American Chemical Society 129 (50), 15438-9 (22 Nov 2007)
Conjugate addition of trifluoroorganic borate K salt of benzofuran, indole and alkene to enals, catalyzed by the imidazolinone-organic catalytic system.
 
An Intramolecular Diels-Alder Strategy for the Asbestinins: Enantioselective Total Syntheses of 11-Acetoxy-4-deoxyasbestinin D and Asbestinin-12
Michael Crimmins and J Ellis
the Journal of Organic Chemistry 73 (5), 1649-60 (05 Oct 2007)
 
Au-Containing All-Carbon 1,4-Dipoles: Generation and [4 + 2] Annulation in the Formation of Carbo-/Heterocycles
Guozhu Zhang et al.
Journal of the American Chemical Society 130 (6), 1814-5 (2008)
Gold complexes to the alpha-propargylic ketone to initiate a nucleophilic addition by the carbonyl group, forming an oxocarbenium ion, which rearranges to generate a tethered carbocation, which along with vinyl-gold complex reacts with various dipolarophiles to generate multi-cyclic compounds.

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